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  7. Tetra-n-butylammonium fluoride, 1M soln. in THF, Thermo Scientific Chemicals

Tetra-n-butylammonium fluoride, 1M soln. in THF, Thermo Scientific Chemicals

46.13 - 440.19

Chemische identificatiekenmerken

CAS 429-41-4
Moleculaire formule C16H36FN
Molecular Weight (g/mol) 261.47
MDL-nummer MFCD00011747
InChI Key FPGGTKZVZWFYPV-UHFFFAOYSA-M
Synoniem tetrabutylammonium fluoride, tbaf, tetrabutylazanium fluoride, tetrabutyl ammonium fluoride, tetra-n-butylammonium fluoride, tetrabutylamine, fluoride, n,n,n-tributylbutan-1-aminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride, n,n,n-tributyl-1-butanaminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride 1:1
PubChem CID 2724141
ChEBI CHEBI:51990
IUPAC Name tetrabutylazanium;fluoride
SMILES [F-].CCCC[N+](CCCC)(CCCC)CCCC
Meer specificaties weergeven

Producten 3
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
Produktcode Merk Aantal Preis Menge & Verfügbarkeit  
11443940
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Thermo Scientific Alfa Aesar
A10588.AC 		25 mL
46.13
25 ml
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11433254
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Thermo Scientific Alfa Aesar
A10588.AE 		100 mL
114.57
100 ml
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11443254
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Thermo Scientific Alfa Aesar
A10588.AP 		500 mL
440.19
500 ml
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Beschreibung

Beschreibung

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Tetra-n-butylammonium fluoride, 1M soln. in THF is used as a reactant for the preparation of triple monoamine reuptake inhibitors as a new generation of antidepressants, oligoribonucleotides with phosphonate-modified linkages, conjugated dienoic acid esters using Suzuki coupling reactions and polyacetylenic glucosides. It plays an important role in aryl alkyl alcohols through Nozaki-Hiyama allylation catalyzed by chiral bipyridyldiol ligands and chromium trichloride. It is also used as a catalyst for the silylation reactions. In addition, it is used as a source of fluoride ion in organic solvents as well as for the deprotection of silyl ether groups.

Solubility
Miscible with terahydrofuran, acetonitrile, dimethyl sulfoxide and organic solvents.

Notes
Store in a cool place. Hygroscopic. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents and oxygen.
Spezifikation

Chemische Identifikatoren

429-41-4
261.47
FPGGTKZVZWFYPV-UHFFFAOYSA-M
2724141
tetrabutylazanium;fluoride
C16H36FN
MFCD00011747
tetrabutylammonium fluoride, tbaf, tetrabutylazanium fluoride, tetrabutyl ammonium fluoride, tetra-n-butylammonium fluoride, tetrabutylamine, fluoride, n,n,n-tributylbutan-1-aminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride, n,n,n-tributyl-1-butanaminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride 1:1
CHEBI:51990
[F-].CCCC[N+](CCCC)(CCCC)CCCC

Spezifikation

Tetra-n-butylammonium fluoride
0.903
C16H36FN
MFCD00011747
3570522
tetrabutylammonium fluoride, tbaf, tetrabutylazanium fluoride, tetrabutyl ammonium fluoride, tetra-n-butylammonium fluoride, tetrabutylamine, fluoride, n,n,n-tributylbutan-1-aminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride, n,n,n-tributyl-1-butanaminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride 1:1
FPGGTKZVZWFYPV-UHFFFAOYSA-M
tetrabutylazanium;fluoride
2724141
261.47
429-41-4
−17°C (1°F)
[CH3(CH2)3]4NF
UN2924
Hygroscopic
Miscible with terahydrofuran,acetonitrile,dimethyl sulfoxide and organic solvents.
[F-].CCCC[N+](CCCC)(CCCC)CCCC
261.47
CHEBI:51990
1M soln. in THF
Videos
Sicherheit und Handhabung

Sicherheit und Handhabung

GHS H Statement
H225-H314-H351-H302-H335
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Suspected of causing cancer.
Harmful if swallowed.
May cause respiratory irritation.

P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P281-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

H225-H314-H335-H336-H351-H373

missing translation for 'dotInformation' : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.

missing translation for 'einecsNumber' : 207-057-2

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures

Produktidentifikator
  • Tetra-n-butylammonium fluoride, 1M solution in THF

Signalwort
  • Gevaar

Gefahrenkategorie
  • Acute toxiciteit Categorie 4
  • Kankerverwekkendheid Categorie 2
  • Ernstig oogletsel/oogirritatie Categorie 1
  • Ontvlambare vloeistof Categorie 2
  • Huidcorrosie/-irritatie Indeling Categorie 1B
  • Dzia anie toksyczne na narzady docelowe Categorie 3

Gefahrenhinweis
  • H225-Licht ontvlambare vloeistof en damp.
  • H302-Schadelijk bij inslikken.
  • H314-Veroorzaakt ernstige brandwonden en oogletsel.
  • H318-Veroorzaakt ernstig oogletsel.
  • H335-Kan irritatie van de luchtwegen veroorzaken.
  • H336-Kan slaperigheid of duizeligheid veroorzaken.
  • H351-Verdacht van het veroorzaken van kanker.
  • EUH019-Kan ontplofbare peroxiden vormen.

Sicherheitshinweis
  • P210-Verwijderd houden van warmte, hete oppervlakken, vonken, open vuur en andere ontstekingsbronnen. Niet roken.
  • P280-Beschermende handschoenen/beschermende kleding/oog­bescherming/gelaatsbescherming dragen.
  • P301+P330+P331-NA INSLIKKEN: de mond spoelen - GEEN braken opwekken.
  • P303+P361+P353-BIJ CONTACT MET DE HUID (of het haar): verontreinigde kleding onmiddellijk uittrekken. Huid met water afspoelen/afdouchen.
  • P305+P351+P338-BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
  • P310-Onmiddellijk een ANTIGIFCENTRUM/arts/ raadplegen.

Ergänzende Informationen
  • MIXTURE LIST-Bevat: Tetrahydrofuran, Tetra-n-butylammonium fluoride

Sicherheitsdatenblatt (SDS)
Dokumentation

Dokumentation

Produktzertifizierungen

RUO – Research Use Only

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