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  6. Lithium tert-butoxide, 99.9% (metals basis), Thermo Scientific Chemicals

Lithium tert-butoxide, 99.9% (metals basis), Thermo Scientific Chemicals

54.07 - 1060.00

Chemische identificatiekenmerken

CAS 1907-33-1
Moleculaire formule C4H9LiO
Molecular Weight (g/mol) 80.055
MDL-nummer MFCD00050479
InChI Key LZWQNOHZMQIFBX-UHFFFAOYSA-N
Synoniem lithium tert-butoxide, lithium 2-methylpropan-2-olate, tert-butoxylithium, lithium tert-butylate, lithium tert-butanolate, tert-butyl alcohol, lithium salt, lithium t-butoxide, 2-methyl-2-propanol lithium salt, 2-propanol, 2-methyl-, lithium salt, lithium 1+ ion 2-methylpropan-2-olate
PubChem CID 23664764
IUPAC Name lithium;2-methylpropan-2-olate
SMILES [Li+].CC(C)(C)[O-]
Meer specificaties weergeven

Producten 4
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
11389618
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Thermo Scientific Alfa Aesar
044133.04 		2 g
54.07
2 gram
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11379618
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Thermo Scientific Alfa Aesar
044133.09 		10 g
121.61
10 gram
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11369618
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Thermo Scientific Alfa Aesar
044133.18 		50 g
488.43
50 gram
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11399618
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Thermo Scientific Alfa Aesar
044133.30 		250 g N/A N/A N/A
Beschrijving

Beschrijving

Lithium tert-butoxide is a mild base used in organic synthesis. It is involved in the alfa-alkylation reaction of ketones with primary alcohols. It is utilized as a catalyst in the reduction of ketones to the corresponding secondary alcohols. It acts as lithium source utilized in the preparation of LixTiyOz thin films. Further, it is used in conjunction with organometallic reagents/catalysts to modify their reactivity and selectivity.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specificatie

Chemische identificatiekenmerken

1907-33-1
80.055
LZWQNOHZMQIFBX-UHFFFAOYSA-N
23664764
[Li+].CC(C)(C)[O-]
C4H9LiO
MFCD00050479
lithium tert-butoxide, lithium 2-methylpropan-2-olate, tert-butoxylithium, lithium tert-butylate, lithium tert-butanolate, tert-butyl alcohol, lithium salt, lithium t-butoxide, 2-methyl-2-propanol lithium salt, 2-propanol, 2-methyl-, lithium salt, lithium 1+ ion 2-methylpropan-2-olate
lithium;2-methylpropan-2-olate

Specificatie

Lithium tert-butoxide
∼150°C (decomposition)
Odorless
C4H9LiO
MFCD00050479
3620018
lithium tert-butoxide, lithium 2-methylpropan-2-olate, tert-butoxylithium, lithium tert-butylate, lithium tert-butanolate, tert-butyl alcohol, lithium salt, lithium t-butoxide, 2-methyl-2-propanol lithium salt, 2-propanol, 2-methyl-, lithium salt, lithium 1+ ion 2-methylpropan-2-olate
LZWQNOHZMQIFBX-UHFFFAOYSA-N
lithium;2-methylpropan-2-olate
23664764
99.9%
1907-33-1
White to Cream
(metals basis)
(CH3)3COLi
UN3206
Air and moisture sensitive
Soluble in toluene,hexane,tetrahydrofuran and methyl tert-butyl ether.
[Li+].CC(C)(C)[O-]
80.055
80.06
Powder
Video's
Veiligheid en behandeling

Veiligheid en behandeling

GHS H Statement
H251-H314-H302
Self-heating: may catch fire.
Causes severe skin burns and eye damage.
Harmful if swallowed.

P210-P240-P241-P260-P264b-P270-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

H228-H302-H314

missing translation for 'dotInformation' : Hazard Class: 4.1; Packaging Group: II

missing translation for 'einecsNumber' : 217-611-5

missing translation for 'rtecsNumber' : UB8520000

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures; Store under Nitrogen

Productidentificatie
  • Lithium tert-butoxide

Signaalwoord
  • Gevaar

Gevarencategorie
  • Acute toxiciteit Categorie 4
  • Ernstig oogletsel/oogirritatie Categorie 1
  • Ontvlambare vaste stof Categorie 2
  • Huidcorrosie/-irritatie Indeling Categorie 1B

Gevarenaanduiding
  • H228-Ontvlambare vaste stof.
  • H302-Schadelijk bij inslikken.
  • H314-Veroorzaakt ernstige brandwonden en oogletsel.
  • H318-Veroorzaakt ernstig oogletsel.
  • EUH014-Reageert heftig met water.

Veiligheidsmaatregel
  • P235+P410-Koel bewaren. Tegen zonlicht beschermen.
  • P280-Beschermende handschoenen/beschermende kleding/oog­bescherming/gelaatsbescherming dragen.
  • P301+P330+P331-NA INSLIKKEN: de mond spoelen - GEEN braken opwekken.
  • P305+P351+P338-BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
  • P310-Onmiddellijk een ANTIGIFCENTRUM/arts/ raadplegen.

Aanvullende informatie
  • MIXTURE LIST-Bevat: Lithium tert-butoxide

SDS
Documentatie

Documentatie

Product Certifications

RUO – Research Use Only

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