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Iodomethane, 99%, stab. with copper, Thermo Scientific Chemicals
CAS: 74-88-4 | CH3I | 141.94 g/mol
46.30 - 432.15
Chemische identificatiekenmerken
CAS | 74-88-4 |
---|---|
Moleculaire formule | CH3I |
Molecular Weight (g/mol) | 141.94 |
MDL-nummer | MFCD00001073 |
InChI Key | INQOMBQAUSQDDS-UHFFFAOYSA-N |
Synoniem | methyl iodide, monoiodomethane, methane, iodo, methyljodid, jod-methan, methyliodide, methyljodide, iodometano, joodmethaan, metylu jodek |
PubChem CID | 6328 |
ChEBI | CHEBI:39282 |
IUPAC Name | iodomethane |
SMILES | CI |
Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
---|---|---|---|---|---|---|---|---|---|
Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
11620222
|
Thermo Scientific Alfa Aesar
A10559.18 |
50 g |
46.30
|
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11440980
|
Thermo Scientific Alfa Aesar
A10559.30 |
250 g |
137.69
|
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
11420980
|
Thermo Scientific Alfa Aesar
A10559.0B |
1000 g |
432.15
|
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Beschrijving
Iodomethane is a methylating agent used for alkylating carbon, oxygen, sulfur, nitrogen and phosphorus nucleophiles. For example, phenol reacts with methyl iodide to give anisole. In the Monsanto process, the insitu formed iodomethane reacts with carbon monoxide in the presence of a rhodium complex to give acetyl iodide, which on hydrolysis yields acetic acid. It reacts with magnesium to form the Grignard reagent, methylmagnesium iodide used in organic synthesis. It finds applications as an intermediate in the manufacture of pharmaceuticals and in phase transfer catalysts.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsIodomethane is a methylating agent used for alkylating carbon, oxygen, sulfur, nitrogen and phosphorus nucleophiles. For example, phenol reacts with methyl iodide to give anisole. In the Monsanto process, the insitu formed iodomethane reacts with carbon monoxide in the presence of a rhodium complex to give acetyl iodide, which on hydrolysis yields acetic acid. It reacts with magnesium to form the Grignard reagent, methylmagnesium iodide used in organic synthesis. It finds applications as an intermediate in the manufacture of pharmaceuticals and in phase transfer catalysts.
Solubility
Miscible with water.
Notes
Light and moisture sensitive. Store in cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, strong bases and oxygen.
Chemische identificatiekenmerken
74-88-4 | |
141.94 | |
INQOMBQAUSQDDS-UHFFFAOYSA-N | |
6328 | |
iodomethane |
CH3I | |
MFCD00001073 | |
methyl iodide, monoiodomethane, methane, iodo, methyljodid, jod-methan, methyliodide, methyljodide, iodometano, joodmethaan, metylu jodek | |
CHEBI:39282 | |
CI |
Specificatie
Iodomethane | |
74-88-4 | |
2.28 | |
Pungent | |
1.53 | |
UN2644 | |
Light sensitive | |
methyl iodide, monoiodomethane, methane, iodo, methyljodid, jod-methan, methyliodide, methyljodide, iodometano, joodmethaan, metylu jodek | |
INQOMBQAUSQDDS-UHFFFAOYSA-N | |
iodomethane | |
6328 | |
141.94 |
Stabilized with copper | |
-67°C | |
41°C to 43°C | |
CH3I | |
MFCD00001073 | |
969135 | |
14,6087 | |
Miscible with water. | |
CI | |
141.94 | |
CHEBI:39282 | |
99% |
Veiligheid en behandeling
GHS H Statement
H301-H331-H351-H312-H315-H335
Toxic if swallowed.
Toxic if inhaled.
Suspected of causing cancer.
Harmful in contact with skin.
Causes skin irritation.
May cause respiratory irritation.
P201-P202-P260-P264b-P270-P271-P280i-P281-P301+P310-P302+P352-P304+P340-P305+P351+P338-P308+P313-P311-P312-P330-P332+P313-P362-P501c
H301+H331-H312-H315-H319-H335-H351
missing translation for 'dotInformation' : Transport Hazard Class: 6.1; Packing Group: I; Proper Shipping Name: METHYL IODIDE
missing translation for 'einecsNumber' : 200-819-5
missing translation for 'rtecsNumber' : PA9450000
missing translation for 'tsca' : Yes
Recommended Storage : Keep cold
- Iodomethane
Signaalwoord
- Gevaar
Gevarencategorie
- Acute toxiciteit Categorie 3
- Acute toxiciteit Categorie 4
- Kankerverwekkendheid Categorie 2
- Huidcorrosie/-irritatie Indeling Categorie 2
- Dzia anie toksyczne na narzady docelowe Categorie 3
Gevarenaanduiding
- H301-Giftig bij inslikken.
- H312-Schadelijk bij contact met de huid.
- H315-Veroorzaakt huidirritatie.
- H331-Giftig bij inademing.
- H335-Kan irritatie van de luchtwegen veroorzaken.
- H351-Verdacht van het veroorzaken van kanker.
Veiligheidsmaatregel
- P201-Alvorens te gebruiken de speciale aanwijzingen raadplegen.
- P280-Beschermende handschoenen/beschermende kleding/oogbescherming/gelaatsbescherming dragen.
- P301+P310-NA INSLIKKEN: onmiddellijk een ANTIGIFCENTRUM/arts/ raadplegen.
- P302+P352-BIJ CONTACT MET DE HUID: met veel water/ wassen.
- P304+P340-NA INADEMING: de persoon in de frisse lucht brengen en ervoor zorgen dat deze gemakkelijk kan ademen.
- P311-Een ANTIGIFCENTRUM/arts/ raadplegen.
Aanvullende informatie
- MIXTURE LIST-Bevat: Methyl iodide
RUO – Research Use Only
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