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Bromotrimethylsilane, 97%, stab. with copper powder or silver wire, Thermo Scientific Chemicals
CAS: 2857-97-8 | C3H9BrSi | 153.094 g/mol
41.61 - 538.68
Chemische identificatiekenmerken
| CAS | 2857-97-8 |
|---|---|
| Moleculaire formule | C3H9BrSi |
| Molecular Weight (g/mol) | 153.094 |
| MDL-nummer | MFCD00000048 |
| InChI Key | IYYIVELXUANFED-UHFFFAOYSA-N |
| Synoniem | trimethylsilyl bromide, trimethylbromosilane, silane, bromotrimethyl, trimethylsilicon bromide, tmsbr, trimethylsilylbromide, bromotrimethyl silane, tmbs, bromo trimethyl silane, tms bromide |
| PubChem CID | 76113 |
| IUPAC Name | bromo(trimethyl)silane |
| SMILES | C[Si](C)(C)Br |
| Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
|---|---|---|---|---|---|---|---|---|---|
| Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
|
11488236
|
Thermo Scientific Alfa Aesar
A15334.09 |
10 g |
41.61
|
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|
11498236
|
Thermo Scientific Alfa Aesar
A15334.18 |
50 g |
131.66
|
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
|
11408246
|
Thermo Scientific Alfa Aesar
A15334.30 |
250 g |
538.68
|
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Beschrijving
Bromotrimethylsilane is used as a mild and selective reagent for cleavage of lactones, epoxides, acetals, phosphonate esters and certain ethers. Further, it is used as a brominating agent and an effective reagent for the formation of silyl enol ethers.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsBromotrimethylsilane is used as a mild and selective reagent for cleavage of lactones, epoxides, acetals, phosphonate esters and certain ethers. Further, it is used as a brominating agent and an effective reagent for the formation of silyl enol ethers.
Solubility
Miscible with carbon tetrachloride, chloroform, dichloroethane, acetonitrile, toluene, dichloromethane and hexane.
Notes
Moisture sensitive. Store in a cool place. Incompatible with strong acids, water and strong oxidizing agents.
Chemische identificatiekenmerken
| 2857-97-8 | |
| 153.094 | |
| IYYIVELXUANFED-UHFFFAOYSA-N | |
| 76113 | |
| C[Si](C)(C)Br |
| C3H9BrSi | |
| MFCD00000048 | |
| trimethylsilyl bromide, trimethylbromosilane, silane, bromotrimethyl, trimethylsilicon bromide, tmsbr, trimethylsilylbromide, bromotrimethyl silane, tmbs, bromo trimethyl silane, tms bromide | |
| bromo(trimethyl)silane |
Specificatie
| 78°C to 80°C | |
| -44°C | |
| 2857-97-8 | |
| (CH3)3SiBr | |
| UN2924 | |
| −3°C (26°F) | |
| Miscible with carbon tetrachloride,chloroform,dichloroethane,acetonitrile,toluene,dichloromethane and hexane. | |
| C[Si](C)(C)Br | |
| 153.094 | |
| 153.09 | |
| Acrid | |
| Moisture sensitive |
| Bromotrimethylsilane | |
| stabilized with copper powder or silver wire | |
| C3H9BrSi | |
| MFCD00000048 | |
| 1731135 | |
| trimethylsilyl bromide, trimethylbromosilane, silane, bromotrimethyl, trimethylsilicon bromide, tmsbr, trimethylsilylbromide, bromotrimethyl silane, tmbs, bromo trimethyl silane, tms bromide | |
| IYYIVELXUANFED-UHFFFAOYSA-N | |
| bromo(trimethyl)silane | |
| 76113 | |
| 97% | |
| 1.425 | |
| 1.183 |
Veiligheid en behandeling
GHS H Statement
H225-H314-H318
Highly flammable liquid and vapour.
Causes severe skin burns and eye damage.
Causes serious eye damage.
P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
H226-H314-H335
missing translation for 'dotInformation' : Hazard Class: 8; Packaging Group: II
missing translation for 'einecsNumber' : 220-672-0
missing translation for 'tsca' : Yes
Recommended Storage : Keep cold
Productidentificatie
Signaalwoord
Gevarencategorie
Gevarenaanduiding
Veiligheidsmaatregel
Aanvullende informatie
- Bromotrimethylsilane
Signaalwoord
- Gevaar
Gevarencategorie
- Ernstig oogletsel/oogirritatie Categorie 1
- Ontvlambare vloeistof Categorie 2
- Huidcorrosie/-irritatie Indeling Categorie 1B
- Dzia anie toksyczne na narzady docelowe Categorie 3
Gevarenaanduiding
- H225-Licht ontvlambare vloeistof en damp.
- H314-Veroorzaakt ernstige brandwonden en oogletsel.
- H318-Veroorzaakt ernstig oogletsel.
- H335-Kan irritatie van de luchtwegen veroorzaken.
- EUH014-Reageert heftig met water.
- EUH208-Bevat . Kan een allergische reactie veroorzaken.
Veiligheidsmaatregel
- P210-Verwijderd houden van warmte, hete oppervlakken, vonken, open vuur en andere ontstekingsbronnen. Niet roken.
- P280-Beschermende handschoenen/beschermende kleding/oogbescherming/gelaatsbescherming dragen.
- P301+P330+P331-NA INSLIKKEN: de mond spoelen - GEEN braken opwekken.
- P303+P361+P353-BIJ CONTACT MET DE HUID (of het haar): verontreinigde kleding onmiddellijk uittrekken. Huid met water afspoelen/afdouchen.
- P305+P351+P338-BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
- P310-Onmiddellijk een ANTIGIFCENTRUM/arts/ raadplegen.
Aanvullende informatie
- MIXTURE LIST-Bevat: Bromotrimethylsilane
RUO – Research Use Only
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