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Allyltrimethylsilane, 98+%, Thermo Scientific Chemicals
56.68 - 723.60
Chemische identificatiekenmerken
| CAS | 762-72-1 |
|---|---|
| Moleculaire formule | C6H14Si |
| Molecular Weight (g/mol) | 114.263 |
| MDL-nummer | MFCD00008635 |
| InChI Key | HYWCXWRMUZYRPH-UHFFFAOYSA-N |
| Synoniem | allyltrimethylsilane, silane, trimethyl-2-propenyl, trimethylallylsilane, silane, allyltrimethyl, allyl trimethylsilane, unii-8b84c337vf, ccris 2649, allyl trimethyl silane, 3-trimethylsilyl propene, allytrimethylsilane |
| PubChem CID | 69808 |
| IUPAC Name | trimethyl(prop-2-enyl)silane |
| SMILES | C[Si](C)(C)CC=C |
| Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
|---|---|---|---|---|---|---|---|---|---|
| Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
|
11497626
|
Thermo Scientific Alfa Aesar
A14662.09 |
10 g |
56.68
10 gram |
Log in om dit product te kopen Registreer vandaag om een webaccount aan te maken | |||||
|
11407636
|
Thermo Scientific Alfa Aesar
A14662.18 |
50 g |
212.06
50 gram |
Log in om dit product te kopen Registreer vandaag om een webaccount aan te maken | |||||
|
11364609
|
Thermo Scientific Alfa Aesar
A14662.30 |
250 g |
723.60
250 gram |
Log in om dit product te kopen Registreer vandaag om een webaccount aan te maken | |||||
Beschrijving
Allyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsAllyltrimethylsilane is involved as a reactant in Hosomi Sakurai reaction for allylation in the presence of Lewis acid. For example, it reacts with cyclohexanone to get 1-allylcyclohexanol. It acts as a nucleophile and is involved in Carbon-Ferrier rearrangement.
Solubility
Miscible with organic solvents. Immiscible with water.
Notes
Store in cool place. Incompatible with strong oxidizing agents and acids.
Chemische identificatiekenmerken
| 762-72-1 | |
| 114.263 | |
| HYWCXWRMUZYRPH-UHFFFAOYSA-N | |
| 69808 | |
| C[Si](C)(C)CC=C |
| C6H14Si | |
| MFCD00008635 | |
| allyltrimethylsilane, silane, trimethyl-2-propenyl, trimethylallylsilane, silane, allyltrimethyl, allyl trimethylsilane, unii-8b84c337vf, ccris 2649, allyl trimethyl silane, 3-trimethylsilyl propene, allytrimethylsilane | |
| trimethyl(prop-2-enyl)silane |
Specificatie
| 85°C to 86°C | |
| 762-72-1 | |
| MFCD00008635 | |
| 906755 | |
| allyltrimethylsilane, silane, trimethyl-2-propenyl, trimethylallylsilane, silane, allyltrimethyl, allyl trimethylsilane, unii-8b84c337vf, ccris 2649, allyl trimethyl silane, 3-trimethylsilyl propene, allytrimethylsilane | |
| HYWCXWRMUZYRPH-UHFFFAOYSA-N | |
| trimethyl(prop-2-enyl)silane | |
| 69808 | |
| ≥98% | |
| 0.717 |
| Allyltrimethylsilane | |
| C6H14Si | |
| UN1993 | |
| −10°C (14°F) | |
| Miscible with organic solvents. Immiscible with water. | |
| C[Si](C)(C)CC=C | |
| 114.263 | |
| 114.27 | |
| 1.408 |
Veiligheid en behandeling
GHS H Statement
H225-H315-H319-H335
Highly flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
H225-H315-H319-H335
missing translation for 'dotInformation' : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
missing translation for 'einecsNumber' : 212-104-5
missing translation for 'tsca' : Yes
Recommended Storage : Ambient temperatures
Gevarencategorie
Gevarenaanduiding
Veiligheidsmaatregel
- AQUATISCH GEVAAR OP LANGE TERMIJN Categorie 2 voor chronische toxiciteit
Gevarenaanduiding
- H411-Giftig voor in het water levende organismen, met langdurige gevolgen.
Veiligheidsmaatregel
- P303+P361+P353-BIJ CONTACT MET DE HUID (of het haar): verontreinigde kleding onmiddellijk uittrekken. Huid met water afspoelen/afdouchen.
- P403+P233-Op een goed geventileerde plaats bewaren. In goed gesloten verpakking bewaren.
RUO – Research Use Only
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