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  7. 3-Bromo-1-trimethylsilyl-1-propyne, 98%, Thermo Scientific Chemicals

3-Bromo-1-trimethylsilyl-1-propyne, 98%, Thermo Scientific Chemicals

CAS: 38002-45-8 | C6H11BrSi | 191.143 g/mol

103.52 - 367.83

Chemische identificatiekenmerken

CAS 38002-45-8
Moleculaire formule C6H11BrSi
Molecular Weight (g/mol) 191.143
MDL-nummer MFCD00134460
InChI Key GAPRPFRDVCCCHR-UHFFFAOYSA-N
Synoniem 3-bromo-1-trimethylsilyl-1-propyne, 3-bromoprop-1-yn-1-yl trimethylsilane, 3-bromo-1-propynyl trimethylsilane, 3-trimethylsilyl propargyl bromide, 3-bromoprop-1-ynyl trimethyl silane, silane, 3-bromo-1-propynyl trimethyl, 3-bromoprop-1-yn-1-yl trimethyl silane, acmc-1cthe, ksc496i3r
PubChem CID 642589
IUPAC Name 3-bromoprop-1-ynyl(trimethyl)silane
SMILES C[Si](C)(C)C#CCBr
Meer specificaties weergeven

Producten 2
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
15430278
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Thermo Scientific Alfa Aesar
H53451.06 		5 g
103.52
5 gram
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15440278
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Thermo Scientific Alfa Aesar
H53451.14 		25 g
367.83
25 gram
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Beschrijving

Beschrijving

3-Bromo-1-trimethylsilyl-1-propyne is used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It acts as a propargylating agent and used for the alkylation of dianion of beta-keto esters at gamma-carbon. It plays an important role in the synthesis of allenic alcohols and terminal conjugated enynes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
3-Bromo-1-trimethylsilyl-1-propyne is used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It acts as a propargylating agent and used for the alkylation of dianion of beta-keto esters at gamma-carbon. It plays an important role in the synthesis of allenic alcohols and terminal conjugated enynes.

Solubility
Immiscible with water.

Notes
Store in cool place. Incompatible with strong oxidizing agents.
Specificatie

Chemische identificatiekenmerken

38002-45-8
191.143
GAPRPFRDVCCCHR-UHFFFAOYSA-N
642589
C[Si](C)(C)C#CCBr
C6H11BrSi
MFCD00134460
3-bromo-1-trimethylsilyl-1-propyne, 3-bromoprop-1-yn-1-yl trimethylsilane, 3-bromo-1-propynyl trimethylsilane, 3-trimethylsilyl propargyl bromide, 3-bromoprop-1-ynyl trimethyl silane, silane, 3-bromo-1-propynyl trimethyl, 3-bromoprop-1-yn-1-yl trimethyl silane, acmc-1cthe, ksc496i3r
3-bromoprop-1-ynyl(trimethyl)silane

Specificatie

44°C to 45°C (2mmHg)
38002-45-8
BrCH2C≡CSi(CH3)3
2037650
3-bromo-1-trimethylsilyl-1-propyne, 3-bromoprop-1-yn-1-yl trimethylsilane, 3-bromo-1-propynyl trimethylsilane, 3-trimethylsilyl propargyl bromide, 3-bromoprop-1-ynyl trimethyl silane, silane, 3-bromo-1-propynyl trimethyl, 3-bromoprop-1-yn-1-yl trimethyl silane, acmc-1cthe, ksc496i3r
GAPRPFRDVCCCHR-UHFFFAOYSA-N
3-bromoprop-1-ynyl(trimethyl)silane
642589
98%
1.17
3-Bromo-1-trimethylsilyl-1-propyne
C6H11BrSi
MFCD00134460
63°C (145°F)
Immiscible with water.
C[Si](C)(C)C#CCBr
191.143
191.14
1.483
Video's
Veiligheid en behandeling

Veiligheid en behandeling

GHS H Statement
H315-H319-H335-H227
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Combustible liquid.

P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c

H227-H315-H319-H335

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures

SDS
Documentatie

Documentatie

Product Certifications

RUO – Research Use Only

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