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2,2,6,6-Tetramethylpiperidine, 98+%, Thermo Scientific Chemicals
CAS: 768-66-1 | C9H19N | 141.258 g/mol
38.19 - 429.58
Chemische identificatiekenmerken
CAS | 768-66-1 |
---|---|
Moleculaire formule | C9H19N |
Molecular Weight (g/mol) | 141.258 |
MDL-nummer | MFCD00005985 |
InChI Key | RKMGAJGJIURJSJ-UHFFFAOYSA-N |
Synoniem | norpempidine, piperidine, 2,2,6,6-tetramethyl, 2,2,6,6-tetramethyl piperidine, unii-44n9s1ycfm, 2,2,6,6-tetramethylpeperidine, 44n9s1ycfm, 2,2,6,6 tetramethyl piperidine, 2,2,6,6-tetramethyl-piperidine, pubchem7259, acmc-209p6i |
PubChem CID | 13035 |
IUPAC Name | 2,2,6,6-tetramethylpiperidine |
SMILES | CC1(CCCC(N1)(C)C)C |
Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
---|---|---|---|---|---|---|---|---|---|
Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
11442988
|
Thermo Scientific Alfa Aesar
A18712.06 |
5 g |
38.19
|
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11452988
|
Thermo Scientific Alfa Aesar
A18712.14 |
25 g |
120.60
|
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
11462988
|
Thermo Scientific Alfa Aesar
A18712.22 |
100 g |
429.58
|
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Beschrijving
2,2,6,6-Tetramethylpiperidine is a hindered base used to prepare metallo-amide bases and selective generation of silylketene acetals. It is used in the preparation of hibarimicinone, (Z)-silylketene acetal and 4-substituted quinazoline. It acts as a precursor to Lithium tetramethylpiperidide and (2,2,6,6-Tetramethylpiperidin-1-yl)oxyl radical.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications2,2,6,6-Tetramethylpiperidine is a hindered base used to prepare metallo-amide bases and selective generation of silylketene acetals. It is used in the preparation of hibarimicinone, (Z)-silylketene acetal and 4-substituted quinazoline. It acts as a precursor to Lithium tetramethylpiperidide and (2,2,6,6-Tetramethylpiperidin-1-yl)oxyl radical.
Solubility
Miscible with water, ether, ethanol and acetic acid. Slightly miscible with chloroform.
Notes
Incompatible with oxidizing agents, bases, strong acids, acid anhydrides, carbon dioxide and acid chlorides.
Chemische identificatiekenmerken
768-66-1 | |
141.258 | |
RKMGAJGJIURJSJ-UHFFFAOYSA-N | |
13035 | |
CC1(CCCC(N1)(C)C)C |
C9H19N | |
MFCD00005985 | |
norpempidine, piperidine, 2,2,6,6-tetramethyl, 2,2,6,6-tetramethyl piperidine, unii-44n9s1ycfm, 2,2,6,6-tetramethylpeperidine, 44n9s1ycfm, 2,2,6,6 tetramethyl piperidine, 2,2,6,6-tetramethyl-piperidine, pubchem7259, acmc-209p6i | |
2,2,6,6-tetramethylpiperidine |
Specificatie
2,2,6,6-Tetramethylpiperidine | |
-59°C | |
152°C to 154°C | |
Amine-like | |
1.444 | |
UN2733 | |
Air Sensitive | |
Miscible with water,ether,ethanol and acetic acid. Slightly miscible with chloroform. | |
CC1(CCCC(N1)(C)C)C | |
141.258 | |
141.26 |
768-66-1 | |
0.832 | |
34°C (93°F) | |
C9H19N | |
MFCD00005985 | |
103296 | |
norpempidine, piperidine, 2,2,6,6-tetramethyl, 2,2,6,6-tetramethyl piperidine, unii-44n9s1ycfm, 2,2,6,6-tetramethylpeperidine, 44n9s1ycfm, 2,2,6,6 tetramethyl piperidine, 2,2,6,6-tetramethyl-piperidine, pubchem7259, acmc-209p6i | |
RKMGAJGJIURJSJ-UHFFFAOYSA-N | |
2,2,6,6-tetramethylpiperidine | |
13035 | |
≥98% |
Veiligheid en behandeling
GHS H Statement
H314-H318-H226-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Flammable liquid and vapour.
Harmful if swallowed.
P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P312-P330-P332+P313-P363-P370+P378q-P501c
H226-H301-H315-H319-H335
missing translation for 'dotInformation' : Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S.
missing translation for 'einecsNumber' : 212-199-3
missing translation for 'rtecsNumber' : TN4220000
missing translation for 'tsca' : Yes
Recommended Storage : Ambient temperatures; Store under Nitrogen
- Gevaar
Gevarencategorie
- Acute toxiciteit Categorie 3
- Acute toxiciteit Categorie 4
- Ernstig oogletsel/oogirritatie Categorie 1
- Ontvlambare vloeistof Categorie 3
- Huidcorrosie/-irritatie Indeling Categorie 1C
Gevarenaanduiding
- H226-Ontvlambare vloeistof en damp.
- H301-Giftig bij inslikken.
- H314-Veroorzaakt ernstige brandwonden en oogletsel.
- H318-Veroorzaakt ernstig oogletsel.
- H332-Schadelijk bij inademing.
Veiligheidsmaatregel
- P210-Verwijderd houden van warmte, hete oppervlakken, vonken, open vuur en andere ontstekingsbronnen. Niet roken.
- P280-Beschermende handschoenen/beschermende kleding/oogbescherming/gelaatsbescherming dragen.
- P301+P330+P331-NA INSLIKKEN: de mond spoelen - GEEN braken opwekken.
- P303+P361+P353-BIJ CONTACT MET DE HUID (of het haar): verontreinigde kleding onmiddellijk uittrekken. Huid met water afspoelen/afdouchen.
- P305+P351+P338-BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
- P310-Onmiddellijk een ANTIGIFCENTRUM/arts/ raadplegen.
RUO – Research Use Only
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