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2,2,6,6-Tetramethylpiperidine, 98+%, Thermo Scientific Chemicals

CAS: 768-66-1 | C9H19N | 141.258 g/mol

38.19 - 429.58

Chemische identificatiekenmerken

CAS 768-66-1
Moleculaire formule C9H19N
Molecular Weight (g/mol) 141.258
MDL-nummer MFCD00005985
InChI Key RKMGAJGJIURJSJ-UHFFFAOYSA-N
Synoniem norpempidine, piperidine, 2,2,6,6-tetramethyl, 2,2,6,6-tetramethyl piperidine, unii-44n9s1ycfm, 2,2,6,6-tetramethylpeperidine, 44n9s1ycfm, 2,2,6,6 tetramethyl piperidine, 2,2,6,6-tetramethyl-piperidine, pubchem7259, acmc-209p6i
PubChem CID 13035
IUPAC Name 2,2,6,6-tetramethylpiperidine
SMILES CC1(CCCC(N1)(C)C)C
Meer specificaties weergeven

Producten 3
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
11442988
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Thermo Scientific Alfa Aesar
A18712.06
5 g
38.19
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11452988
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Thermo Scientific Alfa Aesar
A18712.14
25 g
120.60
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11462988
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Thermo Scientific Alfa Aesar
A18712.22
100 g
429.58
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Beschrijving

Beschrijving

2,2,6,6-Tetramethylpiperidine is a hindered base used to prepare metallo-amide bases and selective generation of silylketene acetals. It is used in the preparation of hibarimicinone, (Z)-silylketene acetal and 4-substituted quinazoline. It acts as a precursor to Lithium tetramethylpiperidide and (2,2,6,6-Tetramethylpiperidin-1-yl)oxyl radical.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2,2,6,6-Tetramethylpiperidine is a hindered base used to prepare metallo-amide bases and selective generation of silylketene acetals. It is used in the preparation of hibarimicinone, (Z)-silylketene acetal and 4-substituted quinazoline. It acts as a precursor to Lithium tetramethylpiperidide and (2,2,6,6-Tetramethylpiperidin-1-yl)oxyl radical.

Solubility
Miscible with water, ether, ethanol and acetic acid. Slightly miscible with chloroform.

Notes
Incompatible with oxidizing agents, bases, strong acids, acid anhydrides, carbon dioxide and acid chlorides.
Specificatie

Chemische identificatiekenmerken

768-66-1
141.258
RKMGAJGJIURJSJ-UHFFFAOYSA-N
13035
CC1(CCCC(N1)(C)C)C
C9H19N
MFCD00005985
norpempidine, piperidine, 2,2,6,6-tetramethyl, 2,2,6,6-tetramethyl piperidine, unii-44n9s1ycfm, 2,2,6,6-tetramethylpeperidine, 44n9s1ycfm, 2,2,6,6 tetramethyl piperidine, 2,2,6,6-tetramethyl-piperidine, pubchem7259, acmc-209p6i
2,2,6,6-tetramethylpiperidine

Specificatie

2,2,6,6-Tetramethylpiperidine
-59°C
152°C to 154°C
Amine-like
1.444
UN2733
Air Sensitive
Miscible with water,ether,ethanol and acetic acid. Slightly miscible with chloroform.
CC1(CCCC(N1)(C)C)C
141.258
141.26
768-66-1
0.832
34°C (93°F)
C9H19N
MFCD00005985
103296
norpempidine, piperidine, 2,2,6,6-tetramethyl, 2,2,6,6-tetramethyl piperidine, unii-44n9s1ycfm, 2,2,6,6-tetramethylpeperidine, 44n9s1ycfm, 2,2,6,6 tetramethyl piperidine, 2,2,6,6-tetramethyl-piperidine, pubchem7259, acmc-209p6i
RKMGAJGJIURJSJ-UHFFFAOYSA-N
2,2,6,6-tetramethylpiperidine
13035
≥98%
Video's
Veiligheid en behandeling

Veiligheid en behandeling

GHS H Statement
H314-H318-H226-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Flammable liquid and vapour.
Harmful if swallowed.

P210-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P312-P330-P332+P313-P363-P370+P378q-P501c

H226-H301-H315-H319-H335

missing translation for 'dotInformation' : Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S.

missing translation for 'einecsNumber' : 212-199-3

missing translation for 'rtecsNumber' : TN4220000

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures; Store under Nitrogen

Signaalwoord
  • Gevaar

Gevarencategorie
  • Acute toxiciteit Categorie 3
  • Acute toxiciteit Categorie 4
  • Ernstig oogletsel/oogirritatie Categorie 1
  • Ontvlambare vloeistof Categorie 3
  • Huidcorrosie/-irritatie Indeling Categorie 1C

Gevarenaanduiding
  • H226-Ontvlambare vloeistof en damp.
  • H301-Giftig bij inslikken.
  • H314-Veroorzaakt ernstige brandwonden en oogletsel.
  • H318-Veroorzaakt ernstig oogletsel.
  • H332-Schadelijk bij inademing.

Veiligheidsmaatregel
  • P210-Verwijderd houden van warmte, hete oppervlakken, vonken, open vuur en andere ontstekingsbronnen. Niet roken.
  • P280-Beschermende handschoenen/beschermende kleding/oog­bescherming/gelaatsbescherming dragen.
  • P301+P330+P331-NA INSLIKKEN: de mond spoelen - GEEN braken opwekken.
  • P303+P361+P353-BIJ CONTACT MET DE HUID (of het haar): verontreinigde kleding onmiddellijk uittrekken. Huid met water afspoelen/afdouchen.
  • P305+P351+P338-BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
  • P310-Onmiddellijk een ANTIGIFCENTRUM/arts/ raadplegen.

SDS
Documentatie

Documentatie

Product Certifications

RUO – Research Use Only

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