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1-(Trimethylsilyl)imidazole, 97%, Thermo Scientific Chemicals
CAS: 18156-74-6 | C6H12N2Si | 140.26 g/mol
20.50 - 308.54
Chemische identificatiekenmerken
| CAS | 18156-74-6 |
|---|---|
| Moleculaire formule | C6H12N2Si |
| Molecular Weight (g/mol) | 140.26 |
| MDL-nummer | MFCD00005280 |
| InChI Key | YKFRUJSEPGHZFJ-UHFFFAOYSA-N |
| Synoniem | n-trimethylsilyl imidazole, 1-trimethylsilyl imidazole, 1-trimethylsilyl-1h-imidazole, tsim, 1h-imidazole, 1-trimethylsilyl, n-trimethylsilylimidazole, trimethylsilyl imidazole, 1-trimethylsilylimidazole, n-trimethylsilyl imidazol, imidazole, 1-trimethylsilyl |
| PubChem CID | 28925 |
| ChEBI | CHEBI:85063 |
| IUPAC Name | imidazol-1-yl(trimethyl)silane |
| SMILES | C[Si](C)(C)N1C=CN=C1 |
| Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
|---|---|---|---|---|---|---|---|---|---|
| Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
|
11488710
|
Thermo Scientific Alfa Aesar
A12512.06 |
5 g |
20.50
|
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|
11444164
|
Thermo Scientific Alfa Aesar
A12512.18 |
50 g |
92.46
|
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
|
11498710
|
Thermo Scientific Alfa Aesar
A12512.22 |
100 g |
148.74
|
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
|
11454164
|
Thermo Scientific Alfa Aesar
A12512.30 |
250 g |
308.54
|
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Beschrijving
1-(Trimethylsilyl)imidazole acts as a silylating agent for alcohols, carbohydrates and 1,3-dicarbonyl compounds. It is a derivatization reagent used for selective silylation of hydroxyl groups and carboxylic acid without affecting the amino group. It employed as an intermediate for the synthesis of imidazole derivatives. It plays an essential role to synthesize polysubstituted chiral spirotetrahydropyrans. It is also used in the quantification of pintol after derivatization by gas chromatography/ mass spectrometry.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications1-(Trimethylsilyl)imidazole acts as a silylating agent for alcohols, carbohydrates and 1,3-dicarbonyl compounds. It is a derivatization reagent used for selective silylation of hydroxyl groups and carboxylic acid without affecting the amino group. It employed as an intermediate for the synthesis of imidazole derivatives. It plays an essential role to synthesize polysubstituted chiral spirotetrahydropyrans. It is also used in the quantification of pintol after derivatization by gas chromatography/ mass spectrometry.
Solubility
Miscible with most common organic solvents. It decomposes in water.
Notes
Moisture and light sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong acids.
Chemische identificatiekenmerken
| 18156-74-6 | |
| 140.26 | |
| YKFRUJSEPGHZFJ-UHFFFAOYSA-N | |
| 28925 | |
| imidazol-1-yl(trimethyl)silane |
| C6H12N2Si | |
| MFCD00005280 | |
| n-trimethylsilyl imidazole, 1-trimethylsilyl imidazole, 1-trimethylsilyl-1h-imidazole, tsim, 1h-imidazole, 1-trimethylsilyl, n-trimethylsilylimidazole, trimethylsilyl imidazole, 1-trimethylsilylimidazole, n-trimethylsilyl imidazol, imidazole, 1-trimethylsilyl | |
| CHEBI:85063 | |
| C[Si](C)(C)N1C=CN=C1 |
Specificatie
| 1-(Trimethylsilyl)imidazole | |
| -42°C | |
| 212°C | |
| Weak | |
| 1.4765 | |
| UN1993 | |
| Moisture sensitive | |
| Miscible with most common organic solvents. It decomposes in water. | |
| C[Si](C)(C)N1C=CN=C1 | |
| 140.26 | |
| CHEBI:85063 | |
| 97% |
| 18156-74-6 | |
| 0.956 | |
| 18°C (64°F) | |
| C6H12N2Si | |
| MFCD00005280 | |
| 606148 | |
| n-trimethylsilyl imidazole, 1-trimethylsilyl imidazole, 1-trimethylsilyl-1h-imidazole, tsim, 1h-imidazole, 1-trimethylsilyl, n-trimethylsilylimidazole, trimethylsilyl imidazole, 1-trimethylsilylimidazole, n-trimethylsilyl imidazol, imidazole, 1-trimethylsilyl | |
| YKFRUJSEPGHZFJ-UHFFFAOYSA-N | |
| imidazol-1-yl(trimethyl)silane | |
| 28925 | |
| 140.26 |
Veiligheid en behandeling
GHS H Statement
H225-H315-H319-H335
Highly flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
H225-H315-H319-H335
missing translation for 'dotInformation' : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
missing translation for 'einecsNumber' : 242-040-3
missing translation for 'rtecsNumber' : NI8700000
missing translation for 'tsca' : Yes
Recommended Storage : Ambient temperatures
Productidentificatie
Signaalwoord
Gevarencategorie
Gevarenaanduiding
Veiligheidsmaatregel
Aanvullende informatie
- 1-(Trimethylsilyl)imidazole
Signaalwoord
- Gevaar
Gevarencategorie
- Acute toxiciteit Categorie 4
- AQUATISCH GEVAAR OP LANGE TERMIJN Categorie 1 voor chronische toxiciteit
- Ernstig oogletsel/oogirritatie Categorie 1
- Ontvlambare vloeistof Categorie 2
- Giftigheid voor de voortplanting BCategorie 1A
- Huidcorrosie/-irritatie Indeling Categorie 1C
Gevarenaanduiding
- H225-Licht ontvlambare vloeistof en damp.
- H302-Schadelijk bij inslikken.
- H314-Veroorzaakt ernstige brandwonden en oogletsel.
- H318-Veroorzaakt ernstig oogletsel.
- H360D-Kan het ongeboren kind schaden.
- H410-Zeer giftig voor in het water levende organismen, met langdurige gevolgen.
Veiligheidsmaatregel
- P210-Verwijderd houden van warmte, hete oppervlakken, vonken, open vuur en andere ontstekingsbronnen. Niet roken.
- P280-Beschermende handschoenen/beschermende kleding/oogbescherming/gelaatsbescherming dragen.
- P301+P330+P331-NA INSLIKKEN: de mond spoelen - GEEN braken opwekken.
- P303+P361+P353-BIJ CONTACT MET DE HUID (of het haar): verontreinigde kleding onmiddellijk uittrekken. Huid met water afspoelen/afdouchen.
- P305+P351+P338-BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
- P310-Onmiddellijk een ANTIGIFCENTRUM/arts/ raadplegen.
Aanvullende informatie
- MIXTURE LIST-Bevat: 1-(Trimethylsilyl)imidazole
RUO – Research Use Only
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