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Tris(trimethylsilyl)silane, 97%, Thermo Scientific Chemicals

34.97 - 437.18

Chemische identificatiekenmerken

CAS 1873-77-4
Moleculaire formule C9H28Si4
Molecular Weight (g/mol) 248.66
MDL-nummer MFCD00077893
InChI Key SQMFULTZZQBFBM-UHFFFAOYSA-N
Synoniem tris trimethylsilyl silane, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilane, tris trimethylsilyl silicon, ttmss, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl-trisilane, hypersilyl, tris trimethylsilyl silyl radical, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilane #, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilan-2-yl
IUPAC Name 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane
SMILES C[Si](C)(C)[SiH]([Si](C)(C)C)[Si](C)(C)C
Meer specificaties weergeven

Producten 3
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
11400627
Bekijk documenten
Thermo Scientific Alfa Aesar
B22457.03
1 g
34.97
1 gram
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11410627
Bekijk documenten
Thermo Scientific Alfa Aesar
B22457.06
5 g
115.58
5 gram
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11420627
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Thermo Scientific Alfa Aesar
B22457.14
25 g
437.18
25 gram
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Beschrijving

Beschrijving

Tris(trimethylsilyl)silane is used in hydrosilylations of carbonyls, radical reactions, reductions of acid chlorides, and carbon-halogen bonds. It acts a mediator of radical reactions and considered to be a nontoxic substitute for tri-n-butylstannane in radical reactions. It forms complexes with transition metals and main group elements. Further, it is utilized in carbon-carbon bond forming reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Tris(trimethylsilyl)silane is used in hydrosilylations of carbonyls, radical reactions, reductions of acid chlorides, and carbon-halogen bonds. It acts a mediator of radical reactions and considered to be a nontoxic substitute for tri-n-butylstannane in radical reactions. It forms complexes with transition metals and main group elements. Further, it is utilized in carbon-carbon bond forming reactions.

Solubility
Miscible with pentane, ether, toluene and tetrahydrofuran. Sparingly miscible with acetone and acetonitrile. Immiscible with water.

Notes
Light sensitive. Incompatible with strong oxidizing agents.
Specificatie

Chemische identificatiekenmerken

1873-77-4
248.66
SQMFULTZZQBFBM-UHFFFAOYSA-N
1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane
C9H28Si4
MFCD00077893
tris trimethylsilyl silane, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilane, tris trimethylsilyl silicon, ttmss, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl-trisilane, hypersilyl, tris trimethylsilyl silyl radical, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilane #, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilan-2-yl
C[Si](C)(C)[SiH]([Si](C)(C)C)[Si](C)(C)C

Specificatie

82°C to 84°C (12mmHg)
1873-77-4
MFCD00077893
1923953
14,9757
Miscible with pentane,ether,toluene and tetrahydrofuran. Sparingly miscible with acetone and acetonitrile. Immiscible with water.
C[Si](C)(C)[SiH]([Si](C)(C)C)[Si](C)(C)C
248.66
97%
Air Sensitive
Tris(trimethylsilyl)silane
C9H28Si4
UN1993
55°C (131°F)
tris trimethylsilyl silane, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilane, tris trimethylsilyl silicon, ttmss, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl-trisilane, hypersilyl, tris trimethylsilyl silyl radical, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilane #, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilan-2-yl
SQMFULTZZQBFBM-UHFFFAOYSA-N
1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane
248.67
1.49
0.806
Video's
Veiligheid en behandeling

Veiligheid en behandeling

GHS H Statement
H226-H315-H319-H335
Flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c

H226-H315-H319-H335

missing translation for 'dotInformation' : Hazard Class: 3; Packaging Group: III

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures; Store under Argon

Productidentificatie
  • Tris(trimethylsilyl)silane

Signaalwoord
  • Waarschuwing

Gevarencategorie
  • Ernstig oogletsel/oogirritatie Categorie 2
  • Ontvlambare vloeistof Categorie 3
  • Huidcorrosie/-irritatie Indeling Categorie 2
  • Dzia anie toksyczne na narzady docelowe Categorie 3

Gevarenaanduiding
  • H226-Ontvlambare vloeistof en damp.
  • H315-Veroorzaakt huidirritatie.
  • H319-Veroorzaakt ernstige oogirritatie.
  • H335-Kan irritatie van de luchtwegen veroorzaken.

Veiligheidsmaatregel
  • P210-Verwijderd houden van warmte, hete oppervlakken, vonken, open vuur en andere ontstekingsbronnen. Niet roken.
  • P280-Beschermende handschoenen/beschermende kleding/oog­bescherming/gelaatsbescherming dragen.
  • P305+P351+P338-BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.

Aanvullende informatie
  • MIXTURE LIST-Bevat: Tris(trimethylsilyl)silane

SDS
Documentatie

Documentatie

Product Certifications

RUO – Research Use Only

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