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Tris(trimethylsilyl)silane, 97%, Thermo Scientific Chemicals
34.97 - 437.18
Chemische identificatiekenmerken
CAS | 1873-77-4 |
---|---|
Moleculaire formule | C9H28Si4 |
Molecular Weight (g/mol) | 248.66 |
MDL-nummer | MFCD00077893 |
InChI Key | SQMFULTZZQBFBM-UHFFFAOYSA-N |
Synoniem | tris trimethylsilyl silane, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilane, tris trimethylsilyl silicon, ttmss, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl-trisilane, hypersilyl, tris trimethylsilyl silyl radical, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilane #, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilan-2-yl |
IUPAC Name | 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane |
SMILES | C[Si](C)(C)[SiH]([Si](C)(C)C)[Si](C)(C)C |
Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
---|---|---|---|---|---|---|---|---|---|
Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
11400627
|
Thermo Scientific Alfa Aesar
B22457.03 |
1 g |
34.97
1 gram |
Log in om dit product te kopen Registreer vandaag om een webaccount aan te maken | |||||
11410627
|
Thermo Scientific Alfa Aesar
B22457.06 |
5 g |
115.58
5 gram |
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11420627
|
Thermo Scientific Alfa Aesar
B22457.14 |
25 g |
437.18
25 gram |
Log in om dit product te kopen Registreer vandaag om een webaccount aan te maken | |||||
Beschrijving
Tris(trimethylsilyl)silane is used in hydrosilylations of carbonyls, radical reactions, reductions of acid chlorides, and carbon-halogen bonds. It acts a mediator of radical reactions and considered to be a nontoxic substitute for tri-n-butylstannane in radical reactions. It forms complexes with transition metals and main group elements. Further, it is utilized in carbon-carbon bond forming reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsTris(trimethylsilyl)silane is used in hydrosilylations of carbonyls, radical reactions, reductions of acid chlorides, and carbon-halogen bonds. It acts a mediator of radical reactions and considered to be a nontoxic substitute for tri-n-butylstannane in radical reactions. It forms complexes with transition metals and main group elements. Further, it is utilized in carbon-carbon bond forming reactions.
Solubility
Miscible with pentane, ether, toluene and tetrahydrofuran. Sparingly miscible with acetone and acetonitrile. Immiscible with water.
Notes
Light sensitive. Incompatible with strong oxidizing agents.
Chemische identificatiekenmerken
1873-77-4 | |
248.66 | |
SQMFULTZZQBFBM-UHFFFAOYSA-N | |
1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane |
C9H28Si4 | |
MFCD00077893 | |
tris trimethylsilyl silane, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilane, tris trimethylsilyl silicon, ttmss, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl-trisilane, hypersilyl, tris trimethylsilyl silyl radical, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilane #, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilan-2-yl | |
C[Si](C)(C)[SiH]([Si](C)(C)C)[Si](C)(C)C |
Specificatie
82°C to 84°C (12mmHg) | |
1873-77-4 | |
MFCD00077893 | |
1923953 | |
14,9757 | |
Miscible with pentane,ether,toluene and tetrahydrofuran. Sparingly miscible with acetone and acetonitrile. Immiscible with water. | |
C[Si](C)(C)[SiH]([Si](C)(C)C)[Si](C)(C)C | |
248.66 | |
97% | |
Air Sensitive |
Tris(trimethylsilyl)silane | |
C9H28Si4 | |
UN1993 | |
55°C (131°F) | |
tris trimethylsilyl silane, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilane, tris trimethylsilyl silicon, ttmss, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl-trisilane, hypersilyl, tris trimethylsilyl silyl radical, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilane #, 1,1,1,3,3,3-hexamethyl-2-trimethylsilyl trisilan-2-yl | |
SQMFULTZZQBFBM-UHFFFAOYSA-N | |
1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane | |
248.67 | |
1.49 | |
0.806 |
Veiligheid en behandeling
GHS H Statement
H226-H315-H319-H335
Flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
H226-H315-H319-H335
missing translation for 'dotInformation' : Hazard Class: 3; Packaging Group: III
missing translation for 'tsca' : No
Recommended Storage : Ambient temperatures; Store under Argon
- Tris(trimethylsilyl)silane
Signaalwoord
- Waarschuwing
Gevarencategorie
- Ernstig oogletsel/oogirritatie Categorie 2
- Ontvlambare vloeistof Categorie 3
- Huidcorrosie/-irritatie Indeling Categorie 2
- Dzia anie toksyczne na narzady docelowe Categorie 3
Gevarenaanduiding
- H226-Ontvlambare vloeistof en damp.
- H315-Veroorzaakt huidirritatie.
- H319-Veroorzaakt ernstige oogirritatie.
- H335-Kan irritatie van de luchtwegen veroorzaken.
Veiligheidsmaatregel
- P210-Verwijderd houden van warmte, hete oppervlakken, vonken, open vuur en andere ontstekingsbronnen. Niet roken.
- P280-Beschermende handschoenen/beschermende kleding/oogbescherming/gelaatsbescherming dragen.
- P305+P351+P338-BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
Aanvullende informatie
- MIXTURE LIST-Bevat: Tris(trimethylsilyl)silane
RUO – Research Use Only
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