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  7. Sodium bis(trimethylsilyl)amide, 2M soln. in THF, Thermo Scientific Chemicals

Sodium bis(trimethylsilyl)amide, 2M soln. in THF, Thermo Scientific Chemicals

85.32 - 335.67

Chemische identificatiekenmerken

CAS 1070-89-9
Moleculaire formule C6H18NNaSi2
Molecular Weight (g/mol) 183.377
MDL-nummer MFCD00009835
InChI Key WRIKHQLVHPKCJU-UHFFFAOYSA-N
Synoniem sodium bis trimethylsilyl amide, n-sodiohexamethyldisilazane, sodium hexamethyldisilazide, nahmds, sodiobis trimethylsilyl amine, sodium bis trimethylsilyl azanide, n-sodium hexamethyldisilazane, sodium-bis trimethylsilyl amide, hexamethyldisilazane sodium salt
PubChem CID 2724254
IUPAC Name sodium;bis(trimethylsilyl)azanide
SMILES C[Si](C)(C)[N-][Si](C)(C)C.[Na+]
Meer specificaties weergeven

Producten 2
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
11358066
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Thermo Scientific Alfa Aesar
L13352.AE 		100 mL
85.32
100 ml
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11368066
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Thermo Scientific Alfa Aesar
L13352.AP 		500 mL
335.67
500 ml
Please to purchase this item. Need a web account? Register with us today!
Beschrijving

Beschrijving

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Sodium bis(trimethylsilyl)amide is a strong base used in organic synthesis for deprotonation reactions and base catalyzed reaction. It is also used to enhance the polymerization of pheneylacetylene in conjunction with rhodium(I) catalysis. It is involved in the generation of enolates, Wittig reagents and carbenes.

Solubility
Miscible with benzene and toluene.

Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents, strong oxidizing agents and oxygen. Dry residue is explosive.
Specificatie

Chemische identificatiekenmerken

1070-89-9
183.377
WRIKHQLVHPKCJU-UHFFFAOYSA-N
2724254
C[Si](C)(C)[N-][Si](C)(C)C.[Na+]
C6H18NNaSi2
MFCD00009835
sodium bis trimethylsilyl amide, n-sodiohexamethyldisilazane, sodium hexamethyldisilazide, nahmds, sodiobis trimethylsilyl amine, sodium bis trimethylsilyl azanide, n-sodium hexamethyldisilazane, sodium-bis trimethylsilyl amide, hexamethyldisilazane sodium salt
sodium;bis(trimethylsilyl)azanide

Specificatie

Sodium bis(trimethylsilyl)amide
C6H18NNaSi2
UN2924
−17°C (1°F)
Miscible with benzene and toluene.
C[Si](C)(C)[N-][Si](C)(C)C.[Na+]
183.377
183.38
Moisture sensitive; May form a precipitate
1070-89-9
MFCD00009835
3629917
sodium bis trimethylsilyl amide, n-sodiohexamethyldisilazane, sodium hexamethyldisilazide, nahmds, sodiobis trimethylsilyl amine, sodium bis trimethylsilyl azanide, n-sodium hexamethyldisilazane, sodium-bis trimethylsilyl amide, hexamethyldisilazane sodium salt
WRIKHQLVHPKCJU-UHFFFAOYSA-N
sodium;bis(trimethylsilyl)azanide
2724254
2M soln. in THF
0.92
Video's
Veiligheid en behandeling

Veiligheid en behandeling

GHS H Statement
H225-H314-H351-H335
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Suspected of causing cancer.
May cause respiratory irritation.

P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

H225-H302-H314-H335-H336-H341-H351

missing translation for 'dotInformation' : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.

missing translation for 'einecsNumber' : 213-983-8

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures; Store under Nitrogen

Productidentificatie
  • Sodium bis(trimethylsilyl)amide, 2M solution in THF

Signaalwoord
  • Gevaar

Gevarencategorie
  • Acute toxiciteit Categorie 4
  • AQUATISCH GEVAAR OP LANGE TERMIJN Categorie 3 voor chronische toxiciteit
  • Kankerverwekkendheid Categorie 2
  • Ernstig oogletsel/oogirritatie Categorie 1
  • Ontvlambare vloeistof Categorie 2
  • Mutageniteit van geslachtscellen Categorie 2
  • Huidcorrosie/-irritatie Indeling Categorie 1B
  • Dzia anie toksyczne na narzady docelowe Categorie 3

Gevarenaanduiding
  • H225-Licht ontvlambare vloeistof en damp.
  • H302-Schadelijk bij inslikken.
  • H314-Veroorzaakt ernstige brandwonden en oogletsel.
  • H318-Veroorzaakt ernstig oogletsel.
  • H335-Kan irritatie van de luchtwegen veroorzaken.
  • H336-Kan slaperigheid of duizeligheid veroorzaken.
  • H341-Verdacht van het veroorzaken van genetische schade.
  • H351-Verdacht van het veroorzaken van kanker.
  • H412-Schadelijk voor in het water levende organismen, met langdurige gevolgen.
  • EUH014-Reageert heftig met water.
  • EUH019-Kan ontplofbare peroxiden vormen.

Veiligheidsmaatregel
  • P210-Verwijderd houden van warmte, hete oppervlakken, vonken, open vuur en andere ontstekingsbronnen. Niet roken.
  • P280-Beschermende handschoenen/beschermende kleding/oog­bescherming/gelaatsbescherming dragen.
  • P301+P330+P331-NA INSLIKKEN: de mond spoelen - GEEN braken opwekken.
  • P303+P361+P353-BIJ CONTACT MET DE HUID (of het haar): verontreinigde kleding onmiddellijk uittrekken. Huid met water afspoelen/afdouchen.
  • P305+P351+P338-BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
  • P310-Onmiddellijk een ANTIGIFCENTRUM/arts/ raadplegen.

Aanvullende informatie
  • MIXTURE LIST-Bevat: Tetrahydrofuran, Sodium bis(trimethylsilyl)amide

SDS
Documentatie

Documentatie

Product Certifications

RUO – Research Use Only

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