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Rhodium(III) 2,4-pentanedionate, Premion™, 99.99% (metals basis), Rh 25.2% min, Thermo Scientific Chemicals

- 800.99

Chemische identificatiekenmerken

CAS 14284-92-5
Moleculaire formule C15H21O6Rh
Molecular Weight (g/mol) 400.23
MDL-nummer MFCD00083144 MFCD00083144
InChI Key DGOINFUDFBWCMX-LNTINUHCSA-K
Synoniem rhodium iii acetylacetonate-rh
PubChem CID 131675882
SMILES [Rh+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O
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Producten 3
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
11300719
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Thermo Scientific Alfa Aesar
010561.02
0.5 g
463.03
0.50 gram
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11390709
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Thermo Scientific Alfa Aesar
010561.03
1 g
800.99
1 gram
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11310719
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Thermo Scientific Alfa Aesar
010561.06
5 g
5 gram for
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Beschrijving

Beschrijving

Rhodium(III) 2,4-pentanedionate is used in catalytic reagents for organic synthesis. Rhodium(III) 2,4-pentanedionate is useful for hydrosilylation of a variety of organic substrates like alkenes, terminal or internal acetylenes, conjugated dienes, alpha, beta -unsaturated aldehydes and allylic compounds. It performs the role of a catalyst in well-known reactions such as transformation processes including hydrogenation, ethanol steam reforming, CO oxidation, and NOx reduction. Rhodium acetylacetonate, as the organic solvent-soluble source of rhodium metal ions, can be used to prepare monodisperse size/shape controlled Rh nanocrystals. Rh nanocrystal monolayers have been reported to show high activity for hydrogenation of vinylcyclohexene to selectively produce ethylcyclohexene. The size/shape controlled nanocrystals find a variety of applications in oil refining processes, chemical synthesis and fuel cell technology.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specificatie

Chemische identificatiekenmerken

14284-92-5
400.23
DGOINFUDFBWCMX-LNTINUHCSA-K
131675882
C15H21O6Rh
MFCD00083144 MFCD00083144
rhodium iii acetylacetonate-rh
[Rh+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O

Specificatie

Rhodium(III) 2,4-pentanedionate
14284-92-5
(metals basis)
MFCD00083144 MFCD00083144
Very soluble in chloroform; Soluble in alcohol; In soluble in water.
[Rh+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O
400.23
400.23
Premion™
263°C to 264°C
Crystalline
C15H21O6Rh
rhodium iii acetylacetonate-rh
DGOINFUDFBWCMX-LNTINUHCSA-K
rhodium(3+) tris((2Z)-4-oxopent-2-en-2-olate)
131675882
99.99%
Rh 25.2% min.
Video's
Veiligheid en behandeling

Veiligheid en behandeling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

H302+H312+H332-H315-H319-H335

missing translation for 'einecsNumber' : 238-192-5

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures

Signaalwoord
  • Waarschuwing

Gevarencategorie
  • Acute toxiciteit Categorie 4
  • Ernstig oogletsel/oogirritatie Categorie 2
  • Giftigheid voor de voortplanting Categorie 2
  • Huidcorrosie/-irritatie Indeling Categorie 2
  • Dzia anie toksyczne na narzady docelowe Categorie 3

Gevarenaanduiding
  • H302-Schadelijk bij inslikken.
  • H312-Schadelijk bij contact met de huid.
  • H315-Veroorzaakt huidirritatie.
  • H319-Veroorzaakt ernstige oogirritatie.
  • H332-Schadelijk bij inademing.
  • H335-Kan irritatie van de luchtwegen veroorzaken.
  • H361-Kan mogelijks de vruchtbaarheid of het ongeboren kind schaden.

Veiligheidsmaatregel
  • P280-Beschermende handschoenen/beschermende kleding/oog­bescherming/gelaatsbescherming dragen.
  • P301+P330+P331-NA INSLIKKEN: de mond spoelen - GEEN braken opwekken.
  • P302+P352-BIJ CONTACT MET DE HUID: met veel water/ wassen.
  • P304+P340-NA INADEMING: de persoon in de frisse lucht brengen en ervoor zorgen dat deze gemakkelijk kan ademen.
  • P305+P351+P338-BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
  • P312-Bij onwel voelen een ANTIGIFCENTRUM/arts/ raadplegen.

SDS
Documentatie

Documentatie

Product Certifications

RUO – Research Use Only

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