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Rhodium(III) 2,4-pentanedionate, Premion™, 99.99% (metals basis), Rh 25.2% min, Thermo Scientific Chemicals
- 800.99
Chemische identificatiekenmerken
CAS | 14284-92-5 |
---|---|
Moleculaire formule | C15H21O6Rh |
Molecular Weight (g/mol) | 400.23 |
MDL-nummer | MFCD00083144 MFCD00083144 |
InChI Key | DGOINFUDFBWCMX-LNTINUHCSA-K |
Synoniem | rhodium iii acetylacetonate-rh |
PubChem CID | 131675882 |
SMILES | [Rh+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O |
Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
---|---|---|---|---|---|---|---|---|---|
Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
11300719
|
Thermo Scientific Alfa Aesar
010561.02 |
0.5 g |
463.03
0.50 gram |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
11390709
|
Thermo Scientific Alfa Aesar
010561.03 |
1 g |
800.99
1 gram |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
11310719
|
Thermo Scientific Alfa Aesar
010561.06 |
5 g |
5 gram for
|
N/A | Please sign in to purchase this item. Need a web account? Register with us today! | ||||
Beschrijving
Rhodium(III) 2,4-pentanedionate is used in catalytic reagents for organic synthesis. Rhodium(III) 2,4-pentanedionate is useful for hydrosilylation of a variety of organic substrates like alkenes, terminal or internal acetylenes, conjugated dienes, alpha, beta -unsaturated aldehydes and allylic compounds. It performs the role of a catalyst in well-known reactions such as transformation processes including hydrogenation, ethanol steam reforming, CO oxidation, and NOx reduction. Rhodium acetylacetonate, as the organic solvent-soluble source of rhodium metal ions, can be used to prepare monodisperse size/shape controlled Rh nanocrystals. Rh nanocrystal monolayers have been reported to show high activity for hydrogenation of vinylcyclohexene to selectively produce ethylcyclohexene. The size/shape controlled nanocrystals find a variety of applications in oil refining processes, chemical synthesis and fuel cell technology.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemische identificatiekenmerken
14284-92-5 | |
400.23 | |
DGOINFUDFBWCMX-LNTINUHCSA-K | |
131675882 |
C15H21O6Rh | |
MFCD00083144 MFCD00083144 | |
rhodium iii acetylacetonate-rh | |
[Rh+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O |
Specificatie
Rhodium(III) 2,4-pentanedionate | |
14284-92-5 | |
(metals basis) | |
MFCD00083144 MFCD00083144 | |
Very soluble in chloroform; Soluble in alcohol; In soluble in water. | |
[Rh+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O | |
400.23 | |
400.23 | |
Premion™ |
263°C to 264°C | |
Crystalline | |
C15H21O6Rh | |
rhodium iii acetylacetonate-rh | |
DGOINFUDFBWCMX-LNTINUHCSA-K | |
rhodium(3+) tris((2Z)-4-oxopent-2-en-2-olate) | |
131675882 | |
99.99% | |
Rh 25.2% min. |
Veiligheid en behandeling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
H302+H312+H332-H315-H319-H335
missing translation for 'einecsNumber' : 238-192-5
missing translation for 'tsca' : Yes
Recommended Storage : Ambient temperatures
- Waarschuwing
Gevarencategorie
- Acute toxiciteit Categorie 4
- Ernstig oogletsel/oogirritatie Categorie 2
- Giftigheid voor de voortplanting Categorie 2
- Huidcorrosie/-irritatie Indeling Categorie 2
- Dzia anie toksyczne na narzady docelowe Categorie 3
Gevarenaanduiding
- H302-Schadelijk bij inslikken.
- H312-Schadelijk bij contact met de huid.
- H315-Veroorzaakt huidirritatie.
- H319-Veroorzaakt ernstige oogirritatie.
- H332-Schadelijk bij inademing.
- H335-Kan irritatie van de luchtwegen veroorzaken.
- H361-Kan mogelijks de vruchtbaarheid of het ongeboren kind schaden.
Veiligheidsmaatregel
- P280-Beschermende handschoenen/beschermende kleding/oogbescherming/gelaatsbescherming dragen.
- P301+P330+P331-NA INSLIKKEN: de mond spoelen - GEEN braken opwekken.
- P302+P352-BIJ CONTACT MET DE HUID: met veel water/ wassen.
- P304+P340-NA INADEMING: de persoon in de frisse lucht brengen en ervoor zorgen dat deze gemakkelijk kan ademen.
- P305+P351+P338-BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
- P312-Bij onwel voelen een ANTIGIFCENTRUM/arts/ raadplegen.
RUO – Research Use Only
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