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Chromyl chloride, 99.99% (metals basis), Thermo Scientific Chemicals

37.27 - 374.87

Chemische identificatiekenmerken

CAS 14977-61-8
Moleculaire formule Cl2CrH4O2
Molecular Weight (g/mol) 158.926
MDL-nummer MFCD00010951
InChI Key HOCPFYCTFLRIAK-UHFFFAOYSA-L
Synoniem chromyl chloride
PubChem CID 101943071
IUPAC Name chromium(2+);dichloride;dihydrate
SMILES O.O.[Cl-].[Cl-].[Cr+2]
Meer specificaties weergeven

Producten 3
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
Produktcode Merk Aantal Prijs Hoeveelheid en beschikbaarheid  
11318508
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Thermo Scientific Alfa Aesar
040517.04
2 g N/A N/A N/A
11398498
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Thermo Scientific Alfa Aesar
040517.09
10 g
107.54
10 gram
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11308508
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Thermo Scientific Alfa Aesar
040517.18
50 g
374.87
50 gram
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Beschrijving

Beschrijving

Highly spin-polarized chromium dioxide (CrO2) thin films were deposited on 100 TiO2 substrates by chemical vapor deposition using chromyl chloride as a precursor. Chromyl chloride (Cr02C12) reacts with cyclohexane solvent at 75 OC to give a dark precipitate along with chlorocyclohexane and a small amount of cyclohexene (in 10.0 and ca. 0.3% yields based on chromium). Chromyl chloride, CrO2C12, oxidizes cyclooctane, isobutane, and toluene under mild conditions (25-60 C). The reactions give chlorinated products (chlorocyclooctane, tert- butyl chloride, and benzyl chloride) and a dark chromium-containing precipitate. Used for Organic oxidations and chlorination, chromium coordination complexes, catalyst for polymerization of olefins. Chromyl chloride in carbon tetrachloride solution reacts in the cold with cyclohexene, cyclopentene, and 1-hexene to give the various isomeric chlorohydrins as the major products.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

  • Organic oxidations and chlorination, chromium coordination complexes, catalyst for polymerization of olefins
Specificatie

Chemische identificatiekenmerken

14977-61-8
158.926
HOCPFYCTFLRIAK-UHFFFAOYSA-L
101943071
O.O.[Cl-].[Cl-].[Cr+2]
Cl2CrH4O2
MFCD00010951
chromyl chloride
chromium(2+);dichloride;dihydrate

Specificatie

117°C
-96.5°C
Liquid
Cl2CrH4O2
UN1758
chromyl chloride
O.O.[Cl-].[Cl-].[Cr+2]
158.926
154.9
Pungent, makes eyes water
1.911g/mL
Chromyl chloride
14977-61-8
(metals basis)
MFCD00010951
14,2248
HOCPFYCTFLRIAK-UHFFFAOYSA-L
chromium(2+);dichloride;dihydrate
101943071
99.99%
Moisture Sensitive
Video's
Veiligheid en behandeling

Veiligheid en behandeling

GHS H Statement
H272-H340-H350-H314-H318-H317
May intensify fire
oxidizer.
May cause genetic defects.
May cause cancer.
Causes severe skin burns and eye damage.
Causes serious eye damage.
May cause an allergic skin reaction.

GHS P Statement
P221-P210-P303+P361+P353-P305+P351+P338-P405-P501a
Take any precaution to avoid mixing with combustibles.
Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do.
Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: I; Proper Shipping Name: CHROMIUM OXYCHLORIDE

missing translation for 'rtecsNumber' : GB5775000

missing translation for 'tsca' : TSCA

SDS
Documentatie

Documentatie

Product Certifications

RUO – Research Use Only

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