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Allylpalladium(II) chloride dimer, Pd 56.0% min, Thermo Scientific Chemicals
59.09 - 924.60
Chemische identificatiekenmerken
| CAS | 12012-95-2 |
|---|---|
| Moleculaire formule | C6H10Cl2Pd2 |
| Molecular Weight (g/mol) | 365.89 |
| MDL-nummer | MFCD00044874 |
| InChI Key | PENAXHPKEVTBLF-UHFFFAOYSA-L |
| Synoniem | allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium |
| PubChem CID | 61538 |
| IUPAC Name | chloropalladium(1+);prop-1-ene |
| SMILES | Cl[Pd].Cl[Pd].c:c:c.c:c:c |
| Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
|---|---|---|---|---|---|---|---|---|---|
| Produktcode | Merk | Aantal | Prijs | Hoeveelheid en beschikbaarheid | |||||
|
11356707
|
Thermo Scientific Alfa Aesar
010005.01 |
0.25 g |
59.09
0.25 gram |
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|
11346707
|
Thermo Scientific Alfa Aesar
010005.03 |
1 g |
185.93
1 gram |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
|
11366707
|
Thermo Scientific Alfa Aesar
010005.06 |
5 g |
924.60
5 gram |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Beschrijving
Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemische identificatiekenmerken
| 12012-95-2 | |
| 365.89 | |
| PENAXHPKEVTBLF-UHFFFAOYSA-L | |
| 61538 | |
| Cl[Pd].Cl[Pd].c:c:c.c:c:c |
| C6H10Cl2Pd2 | |
| MFCD00044874 | |
| allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium | |
| chloropalladium(1+);prop-1-ene |
Specificatie
| Allylpalladium(II) chloride dimer | |
| 120°C (decomposition) | |
| C6H10Cl2Pd2 | |
| 4124623 | |
| allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium | |
| PENAXHPKEVTBLF-UHFFFAOYSA-L | |
| chloropalladium(1+);prop-1-ene | |
| 61538 | |
| Pd 56.0% min. |
| 12012-95-2 | |
| Yellow | |
| MFCD00044874 | |
| Air and moisture sensitive | |
| Very soluble in dichloromethane and dichloroethane; Slightly soluble in toluene,insoluble in waterSoluble in chloroform,benzene,acetone and dichloromethane,dichloroethane and methanol; Slightly soluble in toluene; Insoluble in water. | |
| Cl[Pd].Cl[Pd].c:c:c.c:c:c | |
| 365.89 | |
| 365.85 | |
| Powder |
Veiligheid en behandeling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362
H315-H319
missing translation for 'einecsNumber' : 234-579-8
missing translation for 'rtecsNumber' : RT3510000
missing translation for 'tsca' : No
missing translation for 'storageNote' : 2°C to 8°C
Recommended Storage : Keep cold; Store under Nitrogen
Productidentificatie
Signaalwoord
Gevarencategorie
Gevarenaanduiding
Veiligheidsmaatregel
- di-.Mu.-chlor-bis(eta-ally)palladium
Signaalwoord
- Waarschuwing
Gevarencategorie
- Huidcorrosie/-irritatie Indeling Categorie 2
- Ernstig oogletsel/oogirritatie Categorie 2
- Dzia anie toksyczne na narzady docelowe Categorie 3
Gevarenaanduiding
- H315-Veroorzaakt huidirritatie.
- H319-Veroorzaakt ernstige oogirritatie.
- H335-Kan irritatie van de luchtwegen veroorzaken.
Veiligheidsmaatregel
- P261-Inademing van stof/rook/gas/nevel/damp/spuitnevel vermijden.
- P280-Beschermende handschoenen/beschermende kleding/oogbescherming/gelaatsbescherming dragen.
- P305+P351+P338-BIJ CONTACT MET DE OGEN: voorzichtig afspoelen met water gedurende een aantal minuten; contactlenzen verwijderen, indien mogelijk; blijven spoelen.
- P304+P340-NA INADEMING: de persoon in de frisse lucht brengen en ervoor zorgen dat deze gemakkelijk kan ademen.
- P405-Achter slot bewaren.
- P501-Inhoud/verpakking afvoeren naar .
RUO – Research Use Only
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